HSE

Occupational health — substances, H2S and working in heat

Why hydrogen sulphide becomes more dangerous as the smell disappears, what an exposure limit actually means, why a filter respirator is useless in an oxygen-deficient atmosphere, how silica and welding fume do their damage silently, and why heat stroke is a medical emergency rather than a bad afternoon.

BeginnerOil & GasPetrochemicalPharmaceutical

Standards referencedISO 45001ANSI Z88.2

The hazards on this page differ from most others in one respect: several of them do their damage without producing any sensation at the time. That is why they are controlled by measurement and health surveillance rather than by how the work feels.

Occupational health hazards on a process plantSource: Common industrial hygiene practice; exposure limits are jurisdiction-specific and must be taken from the applicable regulation
9 rows
Hydrogen sulphide (H2S)Rapidly fatal at high concentration; deadens the sense of smell as it risesAcute — minutes or lessDetection, ventilation, escape sets, and never relying on smell
BenzeneCarcinogen affecting the blood-forming systemChronicVery low exposure limit; containment and monitoring
Respirable crystalline silicaIrreversible lung disease from concrete cutting and grindingChronicOn-tool extraction or water suppression at the point of generation
Welding fumeRespiratory disease; now treated as carcinogenicChronic, with acute metal fume fever from zincLocal exhaust ventilation; remove coatings back from the weld
AsbestosFatal lung disease from fibres released when disturbedChronic, decades laterSurvey before demolition or modification; licensed removal
NoisePermanent hearing loss, painless as it developsChronicReduce at source; hearing protection last; survey to find the areas
Hand-arm vibrationIrreversible nerve and blood vessel damage from vibrating toolsChronicTool selection and trigger-time limits — gloves do very little
HeatHeat exhaustion progressing to heat stroke, which is a medical emergencyAcute, within a shiftWork-rest cycles, shade, hydration, midday restrictions
Solvents absorbed through skinSystemic effects that air monitoring alone will not detectChronicGlove material matched to the chemical; biological monitoring

The pattern worth noticing is how many of these do their damage without any sensation at the time. Acute hazards announce themselves; chronic ones do not, which is why they are controlled by measurement and surveillance rather than by how the work feels.

Hydrogen sulphide

H2S is the hazard that defines working practice across much of the oil and gas industry, and it has a property that makes it uniquely treacherous.

A scale of hydrogen sulphide concentration. At low concentrations the smell is strong. Above roughly one hundred parts per million the olfactory nerve is paralysed and the smell disappears entirely, while the danger continues rising to rapidly fatal levels.
The one property that makes H2S uniquely treacherous: the warning stops exactly where the danger starts.

It is also heavier than air, so it collects in low-lying places — pits, sumps, trenches, the bottom of a vessel. A personal monitor worn at the collar can read clear while the atmosphere at the bottom of a trench is lethal, which is why atmospheres are tested at the depth people will actually be.

Escape sets are provided in some areas. They hold a very short duration of air, deliberately, because their only purpose is to get the wearer out — not to let them stay and work.

Exposure limits, and what they do not cover

An occupational exposure limit is an airborne concentration considered acceptable over a stated period — typically an eight-hour average, sometimes with a separate short-term limit for excursions.

Two things about them are worth holding onto.

They are averages, so a brief high exposure can be harmful even where the eight-hour figure looks fine. And they assume the dose arrives by breathing.

Glove material is matched to the specific chemical. A chemical can permeate a glove that shows no visible damage at all, and the figure that matters is breakthrough time rather than thickness.

Respiratory protection, and its one absolute limit

Two families, and confusing them is dangerous.

Air-purifying respirators filter the surrounding air. Cartridges are matched to the contaminant, and they have a finite life.

Supplied-air and self-contained apparatus provide breathing air from elsewhere.

Face fit testing is done for each individual, because air takes the easiest path. A leaking seal admits contaminated air around the edge rather than through the filter, and the protection collapses.

Facial hair at the sealing surface defeats the seal regardless of the test result. That is why clean shaven is a condition of wearing a tight-fitting respirator rather than a preference, and why loose-fitting powered hoods exist for people who cannot meet it.

The dusts and fumes that work slowly

Silica from cutting or grinding concrete causes irreversible lung disease. The dangerous fraction is respirable — too fine to see — so a job that looks clean can be well over the limit.

The effective control is capture at source: on-tool extraction or water suppression. That protects everybody nearby and does not depend on anybody remembering anything, which is exactly why it sits above PPE in the hierarchy.

Welding fume is now treated as carcinogenic, which has raised the standard of ventilation expected rather than leaving it to general air movement. Galvanised and coated steel is worse — heated zinc causes metal fume fever, and removing the coating back from the weld area both reduces the fume and improves the weld.

Asbestos is a survey question before it is a control question. Older plant has it in lagging and gaskets, and an ordinary day of demolition can expose everybody present. The survey happens before the work, not when somebody notices.

Local exhaust ventilation is the common control for all of these, and its capture distance falls away very fast — a hood a metre from the work is doing almost nothing however powerful the fan. It is also examined periodically, because ducts block and fans wear while the system still makes a reassuring noise.

Noise and vibration

Noise-induced hearing loss is permanent and painless as it develops, which is exactly why it needs a survey to find rather than a complaint. Reduce at source first; hearing protection is the last resort and it has to be worn continuously to deliver its rating.

Hand-arm vibration syndrome comes from prolonged use of vibrating tools and damages nerves and blood vessels irreversibly. The controls are tool selection and trigger time limits. Gloves are widely believed to help and do very little.

Both are managed by health surveillance — detecting early signs while the exposure can still be changed, which is the only point at which anything can be done.

Heat

On a Gulf site this is the hazard most likely to injure somebody this week.

The controls are structural rather than personal:

  • Work-rest cycles with shaded rest areas, because heat load accumulates through the shift. Somebody fine at ten can be in trouble at one doing identical work.
  • Hydration, with electrolytes as well as water. Very large volumes of plain water against heavy sweating can dilute sodium dangerously.
  • Midday work bans, set by each Gulf country for the summer months and enforced by inspection with real penalties. They are a compliance matter as well as a health one.
  • Acclimatisation for new arrivals, who are at higher risk for the first week or two.
Workers in orange coveralls and hard hats sitting on benches under a simple shaded shelter of scaffold tube and profiled sheet at the edge of a dusty construction site. A large insulated water cooler stands on a table beside them and several are drinking. Tower cranes and a partly built concrete structure are visible behind in the haze.
This shelter is the control. Heat load accumulates across a shift, so rest has to be scheduled and provided for rather than taken when somebody already feels unwell — by then the margin is gone.

Health surveillance

Where exposure to a known hazard cannot be eliminated, surveillance detects early effects while they can still be acted on — audiometry for noise, lung function for dusts, vibration questionnaires, biological monitoring for absorbed substances.

What to take away

  • H2S deadens the sense of smell as concentration rises. Never use your nose. It collects low.
  • Exposure limits are averages, and a skin notation means air monitoring understates the dose.
  • A filter cannot make oxygen. Oxygen deficiency requires supplied air, always.
  • Face fit testing is per person, and facial hair defeats the seal whatever the test said.
  • Capture dust and fume at source. The respirable fraction of silica is invisible.
  • Noise and vibration damage is permanent and painless. Surveillance finds it while it still matters.
  • Heat stroke is a medical emergency — hot dry skin and confusion, not heavy sweating. Cooling speed decides the outcome.

Check your understanding

6 questions. Nothing is recorded — this is just for you.

1Why is hydrogen sulphide particularly dangerous at high concentrations?
2A filter respirator is worn to enter a tank that has been purged with nitrogen. What is wrong?
3Why is a respirator face fit test carried out for each individual wearer?
4What is the most effective control for silica dust from concrete cutting?
5What distinguishes heat stroke from heat exhaustion?
6A solvent's exposure limit carries a "skin" notation. What does it mean?

#safety#hse#occupational-health#h2s#heat-stress#ppe